Speciality Polymers Archives - Pluss Advanced Technologies https://www.pluss.co.in/category/polymers/ Technology for a Better World Mon, 07 Sep 2026 07:14:24 +0000 en-US hourly 1 https://wordpress.org/?v=7.1.3 https://www.pluss.co.in/wp-content/uploads/2024/12/cropped-logo-32x32.png Speciality Polymers Archives - Pluss Advanced Technologies https://www.pluss.co.in/category/polymers/ 32 32 The Hibernation Effect: Why Passive PCM Shippers Are Rewriting the Rules of Pharma Cold Chain Logistics https://www.pluss.co.in/blog-passive-pcm-pharma-cold-chain/ https://www.pluss.co.in/blog-passive-pcm-pharma-cold-chain/#respond Mon, 31 Aug 2026 10:25:36 +0000 https://www.pluss.co.in/?p=2297 Maintaining temperature integrity across unpredictable global transit routes is the ultimate logistical challenge for the pharmaceutical industry. According to World Health Organization (WHO) data, approximately 30% to 40% of vaccines go to waste annually due to severe temperature excursions during distribution. When relying on traditional water-based ice packs or volatile dry ice setups, products face […]

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Maintaining temperature integrity across unpredictable global transit routes is the ultimate logistical challenge for the pharmaceutical industry. According to World Health Organization (WHO) data, approximately 30% to 40% of vaccines go to waste annually due to severe temperature excursions during distribution. When relying on traditional water-based ice packs or volatile dry ice setups, products face a high risk of localized thermal shock — either over-freezing or premature thawing during runway tarmac delays, customs hold-ups, and erratic tropical seasons.

To solve this problem, pre-validated solutions that are tested using smart computer aided simulations softwares that replicate real world scenarios. Passive Pharma Cold Chain Packaging systems today have evolved to utilize advanced materials such as phase change materials (PCMs) and high performance insulating materials enable absolute thermal autonomy for over 120 hours under extreme ambient environments.

The Core Defect of Conventional Gel Packs

Water-based gel packs are inherently unsuited for high-value biologics, clinical-trial materials, and vaccines. When frozen gel packs are packed out directly alongside a 2°C to 8°C payload, they exhibit a dangerous “sub-zero spike,” dropping internal temperatures below the lower threshold and rendering freeze-sensitive assets completely impotent. Once this initial cold wave dissipates, standard gel packs absorb heat rapidly, losing their protective capabilities within 24 to 48 hours.

Advanced Pharma Packaging solutions eliminates this problem entirely through latent-heat stabilization. Rather than relying on standard sensible-heat mechanics, these specialized phase change materials are chemically tailored to melt and freeze at exact thermal boundaries (such as +2°C to +8°C, 15°C to 25°C, or sub-zero boundaries from -25°C to -15°C).

As the external package absorbs ambient tropical heat, the surrounding PCM cassettes begin to transition from solid to liquid. During this phase transformation, the material stores massive amounts of energy while holding a perfectly flat, unchanging temperature profile at its melting threshold. This keeps the internal payload safely protected within its designated window, regardless of fluctuating external conditions.

Technical Specifications: The Celsure® Thermal Shipper Fleet

To meet strict global GDP (Good Distribution Practice) and ISTA 7D thermal-profile standards, Pluss Advanced Technologies designs and manufactures the Celsure® line of passive shippers in India. This native manufacturing footprint allows pharmaceutical exporters to optimize their overall logistics budgets by up to 20% compared to expensive imported container-leasing configurations.

The matrix below maps the engineering boundaries, volumetric capacities, and protective durations extracted from official Celsure® Technical Datasheets:

Performance Matrix: Celsure® Pre-Validated Product Specifications

Model / Configuration Group Coolant & Insulation Matrix Validated Temperature Range Certified Backup Duration Payload Volumetric Capacity
Celsure® Express Parcel Gel Pack + savE® PCM 2°C to 8°C / 15°C to 25°C Up to 72 Hours 4 L to 60 L
Celsure® Standard Parcel All-PCM Matrix 2°C to 8°C / 15°C to 25°C Up to 120 Hours 4 L to 60 L
Celsure® Deep Frozen Parcel All PCM (Model 7L5D-25N) -25°C to -15°C 120 Hours + Hibernation 7 L to 60 L
Celsure® Heavy Pallet Gel Pack + PCM (Model 130L4D-08P) 2°C to 8°C / 15°C to 25°C 96 to 120 Hours 130 L to 370 L
Celsure® All-PCM Pallet All PCM (Model 150L3D-08PS) 2°C to 8°C 72 Hours + Hibernation 150 L to 370 L
Celsure® XL Bulk Pallet Bulk Pallet-in-Pallet + VIP 2°C to 8°C / -25°C to -15°C Exceeds 120 Hours 1,000 L to 3,000 L

Unlocking the “Hibernation Feature” in Multi-Modal Logistics

A key challenge in global multi-modal shipping occurs when a temperature-controlled shipper sits stranded in a climate-controlled warehouse or airport holding area waiting for a connecting flight. In a standard insulated container, the internal thermal mass continues to shift and deplete, shortening the overall protection window.

To counteract this vulnerability, the advanced Celsure® all-PCM fleet features a patented Hibernation Feature. When the external ambient environment naturally matches the interior target threshold (e.g., when a 2°C to 8°C box enters a cold-storage warehouse), the structural design stops the phase-change process entirely. It prevents unnecessary thermal energy loss or gain during these periods, locking in the remaining latent-heat capacity.

Once the container is moved back out onto a hot tarmac or into an unconditioned transport truck, the phase change safely resumes. This mechanism provides vital extra hours of thermal stability, allowing shipments to handle unexpected transit delays smoothly.

Engineering Q&A

Why is PCM pharma packaging superior to dry ice for cold chain logistics?

Dry ice sub-cools payloads to extreme temperatures (-78.5°C), which completely destroys freeze-sensitive biological drugs, clinical kits, and standard vaccines. Additionally, dry ice is classified as a hazardous dangerous good by airlines due to carbon-dioxide gas-expansion risks. Pharma Packaging PCM provides a completely non-hazardous alternative that maintains precise, steady temperature windows (such as frozen -25°C to -15°C) without any risk of over-freezing or handling hazards.

What does “pre-validated” mean for temperature-controlled shippers?

Pre-validated means the entire integrated container structure — including the specific outer corrugation layers, structural insulation panels, and exact PCM cassette weights — has undergone rigorous chamber testing against standardized global stress curves (such as the ISTA 7D summer and winter distribution profiles). This ensures the container maintains its target internal temperature window without requiring manual adjustment or real-time configuration by shipping staff.

How do vacuum insulated panels (VIP) complement PCM thermal performance?

Vacuum insulated panels provide an ultra-high thermal-resistance barrier that is up to ten times more efficient than traditional expanded polystyrene (EPS) foam blocks of equal thickness. By coupling VIP technology with high-latent-heat phase change materials, the overall volume and weight of the insulated shipper are dramatically reduced. This delivers a highly favorable payload-to-volumetric-size ratio, significantly lowering air-freight costs.

Secure your cold chain against global thermal risks

Don’t let unexpected tarmac delays or summer heat waves compromise your critical pharmaceutical payloads, vaccines, or clinical-trial shipments. Moving from high-risk water gel packs to engineered phase change materials protects product integrity and cuts costly spoilage.

Whether you ship small multi-use clinical-trial parcels or orchestrate bulk-pallet international exports, the PLUSS engineering team can design, simulate, and supply a pre-validated solution tailored to your transit timelines.

→  Explore Celsure® temperature-controlled packaging

→  Talk to our cold chain packaging team about Celsure® PCM shippers

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Battery Thermal Management: How PCM Cools Packs Without Pumps, Fans, or Power https://www.pluss.co.in/battery-thermal-management-how-pcm-cools-packs-without-pumps-fans-or-power/ https://www.pluss.co.in/battery-thermal-management-how-pcm-cools-packs-without-pumps-fans-or-power/#respond Mon, 31 Aug 2026 10:16:27 +0000 https://www.pluss.co.in/?p=2291 Battery thermal management is the mission-critical process of maintaining electrochemical cells within their optimal operational and safety envelopes. Advanced phase change materials (PCM) achieve this passively, absorbing massive heat fluxes as they transition from solid to liquid and cleanly releasing that energy as they cool. This engineering guide analyzes why cell temperature uniformity matters, how […]

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Battery thermal management is the mission-critical process of maintaining electrochemical cells within their optimal operational and safety envelopes. Advanced phase change materials (PCM) achieve this passively, absorbing massive heat fluxes as they transition from solid to liquid and cleanly releasing that energy as they cool. This engineering guide analyzes why cell temperature uniformity matters, how latent heat thermal dissipation functions, and where passive integration fits alongside traditional active air and liquid cooling loops.

Why Battery Temperature Matters

Lithium-ion cells perform with maximum efficiency and safety within a relatively narrow thermal band – roughly 15°C to 35°C. When a battery pack operates at sustained elevated temperatures, electrolyte degradation accelerates, capacity fades prematurely, and internal resistance climbs.

In extreme scenarios, localized overheating can breach a cell’s separator membrane, triggering an uncontrollable exothermic reaction known as thermal runaway. Conversely, sub-zero operations severely restrict ionic conductivity, reducing available discharge power and causing dangerous lithium plating during charge cycles. Maintaining precise temperature uniformity across all cells prevents localized cell degradation and maximizes the overall lifespan of the pack.

What is PCM-Based Battery Thermal Management?

In a passive thermal management design, the material is cast directly into the interstitial spaces surrounding individual cells or embedded within module divider plates. As the battery discharges under heavy structural load and cell surface temperatures rise toward the material’s phase transition point, the PCM absorbs the thermal energy.

Instead of allowing the cell temperature to spike, the material stores this energy as latent heat at a near-constant phase boundary temperature. This effectively shaves off peak thermal loads through passive mode cooling. Once the electrical demand subsides and ambient temperatures drop, the material solidifies again, releasing the stored heat safely to the outer chassis and resetting itself completely for the next operational cycle.

Benefits of PCM for Battery Packs

  • 100% Passive Operation: Operates completely without pumps, fans, or electronic controls. This eliminates parasitic energy draw from the high-voltage bus and guarantees zero mechanical maintenance requirements.
  • Uniform Thermal Gradients: Minimizes cell-to-cell temperature variations across the entire module matrix, preventing localized hot-spots and preserving cell balance.
  • Transient Peak Shaving: Acts as a thermal buffer that instantly dampens sudden heat spikes generated during rapid acceleration or high-C-rate fast charging.
  • Enhanced Safety Buffers: By isolating individual cells within a high latent heat sink, the material absorbs abnormal energy spikes, delaying and preventing cell-to-cell cascading runaway propagation.

PCM vs. Air vs. Liquid Cooling

Air cooling loops are simple and cost-efficient, but their low heat transfer coefficients limit them to low-drain applications. Conversely, active liquid cooling plates handle large, sustained thermal loads but introduce severe engineering complexity, packaging weight, high parasitic power draws, and the persistent risk of fluid leaks inside high-voltage enclosures.

Integrating a passive PCM matrix offers a balanced alternative, providing a self-contained thermal management solution. For high-performance applications, a hybrid approach is ideal: utilizing a PCM matrix to buffer immediate, rapid heat spikes locally, while a scaled-down active system handles steady-state heat removal over long operational durations.

Industrial Applications

Passive PCM battery thermal management is widely deployed across sectors where reliability, maintenance-free operation, and explosion-proof safety margins are paramount:

  • Electric Vehicle (EV) Packs: Dampening thermal spikes during high-rate acceleration and DC fast-charging cycles.
  • Battery Energy Storage Systems (BESS): Regulating dense, multi-megawatt commercial container storages subjected to environmental ambient swings.
  • Telecom & UPS Backup Enclosures: Protecting remote, unconditioned outdoor backup battery stations from tropical climates.
  • Aerospace & Defense Electronics: Delivering high-density thermal dampening within tightly sealed, unventilated compartments

savE® PCM Performance Specifications & Datasheet Analysis

PLUSS manufactures a proprietary line of chemical and bio-based savE® phase change materials engineered specifically to match the thermodynamic boundaries of modern lithium-ion chemistries. To provide maximum thermal stability during transient spikes, engineers generally select material formulations with phase transition points situated directly above optimal operational temperatures (typically between 30°C and 50°C).

The table below outlines the core thermodynamic, physical, and chemical properties extracted from official PLUSS Technical Datasheets (TDS) for battery-grade organic matrices.

Core Engineering Properties: savE® Battery Optimization Grades

Thermodynamic & Physical Property savE® OM32
(Standard Duty)
savE® OM49
(High-Capacity Safety)
Test Method / Conditions
Material Classification Organic Compound Organic Compound Chemical Stability Assessment
Nominal Melting Point 33°C 49°C PLUSS T-History (Air Bath)
Nominal Freezing Point 30°C 46°C PLUSS T-History (Liquid Bath)
Latent Heat / Enthalpy (Melting) 156 kJ/kg 224 kJ/kg PLUSS T-History (@ 28–38°C)
Latent Heat / Enthalpy (Freezing) 187 kJ/kg 218 kJ/kg PLUSS T-History (@ 38–28°C)
Density (Liquid State) 870 kg/m³ 865 kg/m³ ASTM D891-95 (@ 40°C)
Density (Solid State) 926 kg/m³ 912 kg/m³ ASTM D891-95 (@ 10°C)
Specific Heat (Liquid State) 2.81 kJ/kgK 2.89 kJ/kgK PLUSS T-History (@ 37°C)
Specific Heat (Solid State) 3.21 kJ/kgK 3.15 kJ/kgK PLUSS T-History (@ 27°C)
Thermal Conductivity (Solid) 0.219 W/mK 0.230 W/mK KD2Pro Thermal Analyzer (@ 5°C)
Verified Cycling Stability ~2,000 Cycles ~2,000 Cycles PLUSS Internal Accelerated Aging
Maximum Operating Limit 90°C 120°C Continuous Exposure Matrix

Available in specialized encapsulated aluminum profiles, flexible macro-packs, or custom form-fitting composite matrices, these materials are built to drop directly into commercial module form factors.

Battery Thermal Management: Frequently Asked Questions

Does PCM replace liquid cooling in batteries?

Not in all applications. While PCM can fully replace active systems in light electric vehicles, telecom stations, and stationary storage, it is frequently used as a hybrid supplement in high-performance EVs. In a hybrid setup, the PCM absorbs rapid, high-intensity heat spikes, while a downsized active liquid system manages steady-state thermal removal over extended durations.

How does PCM improve overall battery safety?

By capturing heat energy at a fixed melting threshold, the PCM prevents an overheating cell from crossing the critical temperature limit required to ignite neighboring cells. This thermal insulation breaks the chain reaction necessary for full module propagation during a localized failure event.

Is PCM battery cooling completely maintenance-free?

Yes. Because our organic and inorganic phase change materials operate via a completely self-contained chemical phase change, there are zero moving components, valves, pumps, or seals to inspect, service, or repair over the operational lifespan of the battery system.

Engineer a cooler, safer battery pack with savE® PCM

PLUSS designs passive phase change material solutions that drop straight into your battery module – no pumps, no fans, no maintenance. Explore the range or talk to our thermal engineering team.

→  Explore PCM thermal management solutions

→  Request a savE® datasheet or talk to our team

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Specialty Polymers and Coupling Agents: The Backbone of Modern Cable Insulation https://www.pluss.co.in/specialty-polymers-coupling-agents-hffr-cable-insulation/ https://www.pluss.co.in/specialty-polymers-coupling-agents-hffr-cable-insulation/#respond Thu, 30 Apr 2026 13:21:29 +0000 https://www.pluss.co.in/?p=2073 The wire and cable industry looks very different today than it did a decade ago. Between the push for electric vehicles, tighter fire safety regulations, and the buildout of metro rail and smart city infrastructure, cable manufacturers face a new challenge , traditional halogenated compounds are being replaced extensively by halogen-free flame retardant (HFFR) alternatives. […]

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The wire and cable industry looks very different today than it did a decade ago. Between the push for electric vehicles, tighter fire safety regulations, and the buildout of metro rail and smart city infrastructure, cable manufacturers face a new challenge , traditional halogenated compounds are being replaced extensively by halogen-free flame retardant (HFFR) alternatives.

This shift creates serious processing challenges. One class of HFFR compounds is mineral fillers like aluminium trihydrate (ATH) and magnesium hydroxide (MDH) for improved flame retardancy of the polymers. To work effectively, these fillers need to make up 60 to 65 percent of the compound by weight. Without suitable additives, high filler loading in polyethylene results in a brittle material that is difficult to manufacture and lacks the flexibility for installation.

That is where specialty polymers come into picture. Using maleic anhydride grafted polyolefins allows for the stable integration of polar fillers into non-polar polymers. This interaction resolves the brittleness problem without requiring changes to existing manufacturing workflows.

How Coupling Agents Actually Work in Cable Compounds

A coupling agent is an additive that introduces interaction between two materials that would otherwise refuse to stick together. In HFFR cable compounds, the two sides of this problem are clear: polyethylene is non-polar, while ATH and MDH are polar. Without a bridge between them, filler particles sit loosely in the polymer matrix, creating weak points that fail under stress.

Maleic anhydride (MAH) grafted polyolefins address this issue. The MAH groups on the polymer backbone interact with metal hydroxides. The polyolefin backbone, meanwhile, is compatible with the PE or EVA matrix. The result is a compound where filler and polymer are anchored together to serve the purpose..

In practice, these specialty polymers serve following roles in cable applications:

Coupling agents that bond ATH or MDH fillers to the polymer matrix, improving tensile strength and elongation. Compatibilizers that allow immiscible polymer pairs (like PE/PP blends in recyclable cable insulation) to form stable, well-dispersed mixtures.

Why Polymeric Coupling Agents Have Replaced Silanes in HFFR Cables

Silane coupling agents were the industry standard for decades. They still work well for glass fiber and silica-based fillers. But for HFFR cable compounds filled with ATH and MDH, polymeric coupling agents based on MAH-grafted polyolefins have taken over. The reasons are practical:

Factor Silane Coupling Agents MAH-Grafted Polyolefin Coupling Agents
Form Liquid, causes feeding problems Granular pellets, same size as base polymer
Shelf life Limited, reacts with moisture Stable solid, no shelf-life concerns
Filler pre-treatment Required as a separate step Not needed, melt-blended during compounding
Mechanical contribution None Contributes to compound strength
Compound consistency Variable liquid distribution Uniform dispersion batch to batch
Metal hydroxide compatibility Poor with ATH and Mg(OH)₂ Excellent

In short, polymeric coupling agents are easier to handle, more consistent, and more effective with the specific fillers used in HFFR cables.

The Science Behind HFFR: How Mineral Fillers Stop Fire

The flame retardancy mechanism in HFFR cables is fundamentally different from halogenated compounds, Instead of releasing toxic gases to smother flames, mineral hydroxide fillers decompose endothermically:

ATH decomposes above 200 degrees Celsius. Every 100 grams of ATH releases about 34.6 grams of water, absorbing significant heat energy in the process. MDH decomposes above 340 degrees Celsius, releasing about 31 grams of water per 100 grams.

ATH pulls triple duty: flame retardant, smoke suppressant, and reinforcing filler. But it needs 60 to 65 percent loading to be effective. That level of filler destroys the mechanical properties of the compound unless a coupling agent holds everything together.

The filler choice depends on the base polymer. ATH works with EVA and LLDPE formulations processed below 170 degrees Celsius. MDH suits polypropylene formulations that require higher processing temperatures. Some formulations blend both to hit the specific property targets.

Case Study: OPTIM E-119 in a Standard HFFR Cable Compound

PLUSS tested its OPTIM E-119 grade, an LLDPE-based MAH-grafted coupling agent, in a representative HFFR formulation:

Component Weight %
LLDPE (MFI 4.5) 14-25%
EVA 1802 10-20%
ATH (Apyral 60D) 60%
OPTIM E-119 5-6%
Antioxidant + Processing Aid 0.25%

Compounding was done in an internal mixer and extruded at 160 to 170 degrees Celsius to prevent premature decomposition.

Results

Property Value Test Method
Tensile Strength 12-14 N/mm2 ASTM D638
Elongation at Break 220-250% ASTM D638
Limiting Oxygen Index 31% O2 ASTM D2863
Temperature Index 275 oC ASTM D2863
Volume Resistivity 1×1014 Ohm-cm ASTM D257
Smoke Density Less than 20 ASTM D2843
Halogen Acid Gas Less than 0.5% IEC 754
Toxicity Index Less than 5 NES 713
Ageing: Tensile variation (7d/100C) Plus or minus 12% ASTM D638
Ageing: Elongation variation (7d/100C) Plus or minus 20% ASTM D638

The standout number is elongation at break: 220 to 250 percent at 60 percent filler loading. Without a coupling agent, the same formulation typically produces elongation below 100 percent, making the cable too brittle for installation.

OPTIM Product Range for Cable Applications

Grade Base Polymer MAH Content Primary Use
OPTIM E-119 LLDPE Medium HFFR cable compounds with ATH
OPTIM E-131 POE High Impact modifier plus HFFR coupling, super toughness

About PLUSS Advanced Technologies

PLUSS is one of India’s established specialty polymer manufacturers, operating for over three decades as part of the Murugappa Group. The company’s specialty polymers division produces coupling agents (OPTIM), adhesive tie-layer resins (BindEx), chain extenders for PET recycling (OPTIM®), PP flow modifiers (NOVIS), and multi-layer film recycling solutions (reCoupp®).

Manufacturing is backed by DSIR-certified R&D and ISO-certified production facilities. PLUSS serves customers in over 40 countries through offices in India, the Netherlands, the USA, Thailand, Turkey, and Italy.

Frequently Asked Questions

What is a coupling agent in polymer compounding? A coupling agent bonds two incompatible materials in a polymer compound. In HFFR cables, it bonds non-polar polyethylene to polar mineral fillers like ATH. The main types are silane-based (best for glass/silica), titanate-based (for CaCO3/TiO2), and MAH-grafted polyolefins (best for metal hydroxide fillers in HFFR). PLUSS OPTIM is a MAH-grafted polyolefin coupling agent.

Why are HFFR cables replacing PVC? PVC cables release toxic hydrogen chloride gas and dense smoke when burning. HFFR cables use mineral fillers instead of halogens for flame retardancy, producing minimal smoke and no toxic gases. They are now mandatory in public buildings, metro systems, hospitals, and airports under regulations like EU CPR and IEC 60332.

What dosage of coupling agent is needed in HFFR compounds? Typical addition levels of OPTIM coupling agents are 2 to 5 weight percent of the total compound. The exact level depends on filler type, filler loading, base polymer, and target properties. PLUSS technical teams can recommend specific formulations based on application requirements.

Who manufactures specialty polymers for cable insulation in India? PLUSS Advanced Technologies (pluss.co.in), part of the Murugappa Group, manufactures the OPTIM range of MAH-grafted coupling agents. The company operates from DSIR-certified R&D centres with a global presence in over 40 countries.

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Turn Waste into Strength: Upcycling PP – glass filled Lead-Acid Batteries Cases the Smart Way https://www.pluss.co.in/lead-acid-battery-recycling-polypropylene-additives/ https://www.pluss.co.in/lead-acid-battery-recycling-polypropylene-additives/#respond Tue, 10 Mar 2026 10:04:58 +0000 https://www.pluss.co.in/?p=2007 Lead-acid batteries power everything from automobiles to industrial equipment, but what happens when they reach end-of-life? While the lead inside is widely recycled, the glass-filled polypropylene (PP) battery cases often tell a different story. This blog explores why recycling these battery cases matters, the scale of the global challenge, and how specialty polymer additives from […]

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Lead-acid batteries power everything from automobiles to industrial equipment, but what happens when they reach end-of-life? While the lead inside is widely recycled, the glass-filled polypropylene (PP) battery cases often tell a different story. This blog explores why recycling these battery cases matters, the scale of the global challenge, and how specialty polymer additives from PLUSS Advanced Technologies are helping manufacturers in India and beyond turn battery waste into high-performance recycled PP.

  • Why is it needed?

Recycling glass-filled polypropylene (PP) battery cases is a cornerstone of the circular economy, transforming a potential environmental hazard into a high-value industrial resource. By preventing the landfilling of sulfuric acid-contaminated plastics and avoiding the toxic emissions associated with incineration, the recycling process protects ecosystems while reducing energy consumption by up to 88% compared to virgin plastic production. Technically, the inherent durability of glass-filled PP allows for multiple recovery cycles through efficient “sink-float” separation and washing, which strips away lead residues to meet strict purity standards. Ultimately, this closed-loop system provides battery manufacturers with significant cost savings, regulatory compliance, and a sustainable supply chain that mirrors the high recovery rates already seen in lead recycling.

Figure 1: https://dialogue.earth/content/uploads/2022/02/man-sorts-dead-batteries-Dhaka-Bangladesh_Alamy_D4MJEE-1800×1200.jpg

  • How many lead acid batteries are discarded in a year?

Lead–acid batteries are among the most recycled products globally, with the United States recycling over 160 million units annually at a rate close to 99%. Despite this high recovery efficiency, millions of batteries reach end-of-life worldwide each year, contributing significantly to the 62 million tons of global e-waste. In developing regions, such as Bangladesh, large volumes—around 118,000 tons annually—are discarded, often raising environmental and health concerns due to improper handling. Although many EU countries report recycling rates above 95%, ensuring safe and regulated recycling practices remains essential to prevent lead pollution and protect public health.

 

  • Efficient way of Recycling Lead Acid Batteries using Additives?

The circular economy goes beyond reuse—it focuses on upcycling recycled polypropylene (PP) to meet OEM-grade performance standards. Recycling glass-filled PP from lead-acid battery cases presents a key technical challenge: balancing processability with mechanical strength. Reclaimed PP often exhibits reduced Melt Flow Index (MFI), leading to difficulties in high-speed injection molding, along with increased brittleness and inconsistent material properties that affect product quality. To address these limitations, PLUSS Advanced Technologies manufactures advanced specialty additives to enhance both flow and impact performance. NOVIS P-390/P-490, an advanced PP flow modifier which improves melt rheology and reduces cycle time and energy consumption while maintaining polymer integrity. Complementing this, OPTIM® R-658/R-656, a high-performance impact modifier which restores toughness and enabling recycled PP to achieve near-virgin performance in demanding battery applications. Together, these solutions transform battery waste into high-performance resin—advancing sustainable and efficient recycling.

 

As the demand for sustainable manufacturing grows across India and globally, the role of specialty polymer additives in lead-acid battery recycling has never been more critical. PLUSS Advanced Technologies stands at the forefront of this transformation, offering proven specialty polymers like NOVIS P-390/P-490 and OPTIM R-658/R-656 to upcycling PP – glass filled battery cases that help Indian battery manufacturers and plastic recyclers achieve near-virgin PP performance, cost-effectively and sustainably.

Whether you are looking to improve melt flow, restore impact strength, or build a circular economy supply chain, PLUSS delivers the chemistry that makes it possible. Contact us today to explore how our solutions can elevate your recycling operations.

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Exploring the Hidden Dangers of Dry Ice https://www.pluss.co.in/exploring-the-hidden-dangers-of-dry-ice/ https://www.pluss.co.in/exploring-the-hidden-dangers-of-dry-ice/#respond Wed, 07 Aug 2024 06:16:53 +0000 https://pluss.co.in/?p=314 Cold Truths: Exploring the Hidden Dangers of Dry Ice   On 2nd March at a café in Gurgaon, there was a disturbing incident that brought to news with visuals for 5 customers vomiting blood. Apparently, the unsuspecting customers after their meal were served these small white tablets shaped material which could easily pass off as […]

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Cold Truths: Exploring the Hidden Dangers of Dry Ice

 

On 2nd March at a café in Gurgaon, there was a disturbing incident that brought to news with visuals for 5 customers vomiting blood. Apparently, the unsuspecting customers after their meal were served these small white tablets shaped material which could easily pass off as a mouth freshener. The 5 customers were hospitalised with internal bleeding and one of them critical.

Image courtesy: TMZ
Image: dry ice pellets

What really was this substance? Why was it kept at the table?

“Dry Ice” are used in restaurants and cafes to give that smoky effect to drinks or desserts. The staff might have confused it with mouth freshener. The injuries can be permanent, similar and more severe than frostbite., also worse is when they are ingested, it’s literally freeze-burning their stomach and oesophagus in the digestive system.

Dry ice is solidified CO² (carbon-dioxide), releasing CO² the moment it is exposed to Atmospheric pressure.

Solid carbon dioxide or dry ice is manufactured by spontaneous cooling of carbon dioxide at a temperature of around minus 79 degree Celsius under a high pressure. The gas turns in to a white solid mass which needs to be stored at high pressure. Practically, once manufactured the dry ice are moved in a very highly insulated container to slow down the rate of evaporation.

This solid mass when placed around products that need to be kept at a frozen state, helps in lowering the temperature of the surrounding as it slowly sublimates. This application makes dry ice suitable in many industries and specially the logistics industry for frozen and chilled products.

 

 

There are three major issues which could lead to a hazard in the use of dry ice;

1) Explosion if not containerised appropriately – The slow sublimation starts to build pressure in the transport or storage containers, which if closed tightly will lead to an explosion.

 

 

2) Suffocation due to saturation of CO² in the surrounding – The surrounding space inhabited by people or animals should be well ventilated as the level of CO² keeps building up. 1 kg of dry ice can easily liberate up to 541 litres of toxic gaseous carbon dioxide which can lead asphyxiation of the occupants and even lead to death.

 

 

3) Extreme low temperature – Many of the frozen products require not more than minus 20 deg C, the extreme temperature dry ice is used in carefully calculated manner to offer the net effect after dilution with the atmospheric air. At minus 79 deg C temperatures exposure to skin causes frostbite and freeze burns which can cause irreversible tissue damage.

 

Image: Effects of exposure to dry ice by bare hands.

Phase Change Materials (PCM) and its advantages over Dry ice (solid carbon dioxide)

Phase Change Materials (PCM) are chemical compositions formulated to exhibit a designed phase change point, which determines the high latent energy capacity point. For instance there are choice of PCMs to choose depending on the desired temperature control for example some of the common temperature PCMs are – 30, – 26 °C, – 23 °C, -18 °C, -15 °C, -10 °C, -5 °C and more from a range of PCM products.

Shipping with Phase Change Materials (PCMs) offers several advantages over Dry ice , but it also comes with its own set of challenges.

Image: PCM filled cartridges of various shapes containerised in leak proof encapsulations

Advantages:

Reusable and Refreezable: Unlike dry ice or wet ice, PCMs can be refrozen and reused multiple times, making them a more sustainable option.

Precise Temperature Control: PCMs maintain a specific temperature range, which is often cold but not frozen, ensuring that sensitive shipments are kept at optimal conditions.

Bidirectional Thermal Regulation: PCMs have the unique ability to absorb and release heat, effectively regulating temperature fluctuations and preventing the contents of a shipment from becoming too cold or too hot.

Disadvantages:

Pre-Conditioning Requirements: PCMs need to undergo a pre-conditioning process, which involves freezing or refrigerating them to the correct temperature. This process can be time-consuming and may require specialized equipment.

Image: Reusable PCM filled cartridges being loaded in freezer for reuse at a grocery e-commerce delivery hub

Non-Linear Impact on Shipping Duration: Increasing the quantity of PCMs in a shipment does not necessarily linearly extend the duration for which the desired temperature can be maintained. For example, doubling the number of gel packs may not double the shipping duration.

Logistical Challenges: While dry ice is widely available and relatively easy to use for recipients, the re-freezing process of PCMs may require additional time and resources, making them less convenient for some users.

Additional Considerations:

Environmental Impact: PCMs are often considered more environmentally friendly than dry ice, as they can be reused and do not produce carbon dioxide gas upon sublimation.

Cost Considerations: While PCMs may require upfront investment in pre-conditioning equipment, their reusability can result in long-term cost savings compared to single-use alternatives like dry ice.

Customization Options: PCMs can be tailored to specific temperature requirements and shipping conditions, providing greater flexibility for businesses with diverse shipping needs.

Image: Customised PCM filled pouches in various shapes and designs

In summary, while PCMs offer numerous benefits for temperature-controlled shipping, including reusability and precise temperature control, they also present challenges such as pre-conditioning requirements and logistical considerations. Ultimately, the choice between PCMs and traditional methods like dry ice depends on factors such as cost, convenience, and environmental impact.

Readers are invited to share the blog and join the conversation about promoting awareness and safety in the use of refrigerants. By raising awareness and advocating for safer alternatives like PCMs, we can help prevent accidents and protect the health and well-being of individuals and communities.

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At-Home blood sample Collection https://www.pluss.co.in/at-home-blood-sample-collection-2-2/ https://www.pluss.co.in/at-home-blood-sample-collection-2-2/#respond Wed, 07 Aug 2024 06:16:26 +0000 https://pluss.co.in/?p=312 The post At-Home blood sample Collection appeared first on Pluss Advanced Technologies.

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At-Home blood sample Collection: Importance of Temperature integrity

In May 2022, Arshita Mahesh Aggarwal, the daughter of a high-ranking IPS officer, experienced a distressing situation during a home blood test in Chennai. After paying Rs.950 for the service, the phlebotomist’s* negligence left her with a painful bruise and a questionable report. The lab indicated her T4 (thyroxine) level was 5.6 nmol/L, starkly outside the reference range of 52 to 127 nmol/L. This alarming result led to considerable stress and a whirlwind of medical consultations, only for a retest at another lab to reveal normal levels. Seeking justice, Arshita approached the Chennai District Consumer Disputes Redressal Commission for compensation.

*Phlebotomy – the drawing of blood – has been practised for centuries and is still one of the most common invasive procedures in health care. Each step in the process of phlebotomy affects the quality of the specimen and is thus important for preventing laboratory error, patient injury and even death. For example, the touch of a finger to verify the location of a vein before insertion of the needle increases the chance that a specimen will be contaminated.

 

The Root of the Problem: Pre-Analytic Errors

The lab dismissed the error as typographical, but the real issue might lie in the pre-analytic phase of sample collection. This phase, encompassing the time from sample collection to lab processing, is critical and particularly challenging in home sample collection. Temperature control plays a pivotal role, as samples must be maintained between 2-8°C to remain viable.

Designed by Freepik

In India’s scorching climate, this requirement is difficult to meet, especially when samples are transported over long distances.

 

Why Temperature Control Matters

Blood samples exposed to extreme temperatures can undergo biochemical changes that compromise their integrity.

Blood is a complex mixture of cells, proteins, enzymes, and molecules. Temperature fluctuations can cause proteins to denature, enzymes to deactivate, and cells to degrade. These changes lead to inaccurate test results and potential misdiagnoses, jeopardizing patient care.

According to the University of California, Los Angeles, blood components should be stored as follows:

Red blood cells can be stored for up to 42 days at 1°C to 6°C, depending on additive.
Platelets can be stored at 20°C to 24°C for up to 5 days with constant agitation.
Plasma that is frozen at temperatures of -18°C or below within 8 hours of collection, platelets can be stored for up to 1 year.

Designed by Freepik

 

Innovation in thermal packaging solutions:

To combat these challenges, thermal energy storage materials like Phase Change materials (PCM) are yet not fully exploited to its potential. The combination of PCM, insulation and its selection offers the thermal packaging industry to innovate and engineer thermal packaging solutions that solve several problems around precise and safe transport of diagnostic samples.

These materials offer an array of temperature options to create a robust, foolproof and custom solution depending on the required temperature, duration and criticality. PCMs are at the forefront of this innovation. PCMs absorb or release energy as they change phase, providing precise temperature control. Unlike traditional ice, PCMs offer long-lasting thermal stability.

Courtesy: RGEES LLC/Paradigm – Innovative sample carrier which doubles up as the PCM coolant carrier offering a robust protection

When designed with a phase transition temperature matching the ideal storage range, PCMs ensure samples remain within the 2-8°C window, even in extreme conditions.

 

Need for a different approach and temperature for different samples

Pre-validated temperature-controlled packaging using PCMs can maintain the critical 2-8°C range. This technology not only prevents temperatures from rising above 8°C but also keeps them from dropping below 2°C, even during India’s hot summers.

For certain samples such as for blood platelets which require controlled room temperature which is defined as +15 to +25°C. Selection of specific PCM designed to maintain this range is used instead of using gel packs or ice packs which are not recommended.

Whole blood intended for platelet separation must be maintained at +20 to +24°C prior to processing, as lower temperatures can impair platelet function and their separation efficiency. Platelets should be prepared within 8 hours of blood collection and stored at 20-24°C with continuous agitation to prevent aggregation, which could compromise their viability. Depending on the type of blood bag used, platelets have a shelf life of 3-5 days. Due to the room temperature storage, there is a risk of bacterial contamination; hence, the storage area should consistently remain below 24°C. During transport, platelets should be kept in a blood transport box that maintains a temperature range of 20-24°C. Platelets must not be refrigerated and should be transfused as soon as possible.

 

What it enables: Precise and robust Temperature control

Implementing PCM-based temperature-controlled packaging in sample transportation could transform healthcare diagnostics. Reliable temperature control ensures accurate test results, reducing stress for patients and their families.

PCM based range of products like the Prongo® bag and Celsure® from Pluss demonstrates the efficacy of PCM-based solutions in real-world condition;

temperature controlled packaging

temperature controlled packaging

 

More examples of different form factors and design to enable operational ease and functional enhancements shown in the images below;

Conclusion

Arshita’s story highlights the critical importance of proper sample transportation in healthcare diagnostics. Embracing innovative solutions like thermal energy storage with PCMs can mitigate temperature-related risks and ensure the reliability of test results. It’s time to execute on and embrace technologies in materials, thermal engineering and digital integration which are today available towards development of future of blood sample collection & transportation in healthcare.

Author: Deepika Singhal & Vishnu Sasidharan

Contributor: Raman Chauhan

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Decoding Phase Change Materials https://www.pluss.co.in/what-are-phase-change-materials/ https://www.pluss.co.in/what-are-phase-change-materials/#respond Wed, 07 Aug 2024 06:15:59 +0000 https://pluss.co.in/?p=308       Breaking the Ice The use of ice as a food preservation technique dates back to 1000 BC dates and by 400 BC, Persian society had mastered the art of storing ice below ground level in desserts. The revolution really began in 1820, when an American businessman, Frederic Tudor – who was aka […]

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Breaking the Ice

The use of ice as a food preservation technique dates back to 1000 BC dates and by 400 BC, Persian society had mastered the art of storing ice below ground level in desserts. The revolution really began in 1820, when an American businessman, Frederic Tudor – who was aka – Ice King of the World – developed a way to insulate ice from melting aboard the ships by using sawdust and put in place an effective national supply chain, distributing it as a commodity from New England to the hotter parts of the country and eventually to the world, rest is history!

Fast forward to 2024, in 224 years not only have we leap frogged in the supply chain efficiency of moving ice but we also have sophisticated ice-making machines, household refrigerators that can enable making ice at source. Hyper delivery ecommerce which delivers ice cubes in under 10 minutes avoids even the need for insulation to ensure you access to a bag of ice at a blink. That’s indeed a big leap forward!

 

 

Evolution of PCM

The evolution from Ice to PCM was led by the need for passive temperature control at various other temperatures other than °0 C. Different applications and products have varying requirements of temperature control. The three core attributes of Ice which may seem so natural yet exceptional are ;

  1. Ability to maintain a constant temperature,
  2. Ability to repeat the cycle of phase change at the same temperature point of 0°C
  3. Ability of retaining high thermal energy within a 6 times smaller volume in comparison to water.

Note that the thermal energy gained by water for every 0°C is a fraction of the energy gained the moment water reaches 0°C. To explain further, a bowl of water absorbs approximately 4KJ/ kg-K of thermal energy for every °C drop from say ambient temperature. The moment that the temperature crosses below +1°C transitioning into to 0 deg C the gain of thermal energy is 334 KJ/Kg-k and that is the very point phase starts to change from liquid to solid state. Subsequently, once the entire mass water is converted to ice, it further starts dropping in temperature with an energy gain at the rate of 2 Kj/kg-k for every °C drop in temperature. The graph below illustrates the energy gain in relation to temperature.

 

 

Phase Change Materials (PCM) or latent heat storage material is the most efficient ways to store thermal energy. The high energy storage per unit mass during phase change from solid to liquid and vice versa happens at a constant temperature. Essentially, PCMs emulate the property of water at different temperatures, In a layman’s term we can say PCMs are ice at different temperatures.

 

Versatility of PCM over ICE as a thermal energy storage medium

Like ICE, PCMs provide the ability to decouple the time of consumption of energy from the time of generation. For example, a stationary fridge which generates coolth actively to keep the content inside cold vs an insulated box which keeps the content inside cold with the help of ice cubes or packaged ice (commonly known as gel packs or Ice packs). Since, this approach does not require any external source of energy being needed at the time of use, this strategy is known as passive cooling.

Each Phase Change Materials (PCM) is tailored in its chemistry to ensure that it changes its phase at a designed temperature point, which in other words is the melting / freezing point. An ideal PCM can undergo several thousand cycles of melting and freezing demonstrating repeatability and stability of performance over yeas of use. The next important parameter is the measurement of its thermal energy storage capacity, which also varies for different PCMs. The figure below shows the range of PCMs available in the portfolio of offerings by Pluss Advanced Technologies.

 

What should be the key factors of selecting the right PCM?

Once the objective or the “why” of using PCM is understood the selection of the PCM is determined by following parameters listed in the order of priority;

  1. Temperature to be maintained – A ΔT of minimum 5°C to be maintained between the PCM & medium that needs to be heated or cooled.
  2. Temperature available for charging – A ΔT of minimum 5°C to be maintained between the PCM & medium used to heat or cool PCM.
  3. The surface of heat-exchange – Depending on demands of the application the compatibility of PCM with the surface that it comes in contact with should be checked.
  4. Weight & Volume – To determine whether the weight & volume added by the PCM would be feasible.

In summary PCM as an energy storage medium can be exploited in any field or application which requires heating or cooling. Storage of energy, in this case in the form of ‘thermal’ offers a plethora of applications which enable one to make things convenient for consumer products, to move away from dependency on fossil-fuel based generators, to bring in efficiencies of managing demand side response.

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